Fluoromethane

Fluoromethane
Stick model of fluoromethane
Stick model of fluoromethane
Spacefill model of fluoromethane
Spacefill model of fluoromethane
Names
IUPAC name
Fluoromethane
Other names
Freon 41

Methyl fluoride
Halocarbon 41

Monofluoromethane
Identifiers
CAS Number
  • 593-53-3 checkY
3D model (JSmol)
  • Interactive image
Abbreviations R41
Beilstein Reference
1730725
ChEBI
  • CHEBI:28826 checkY
ChEMBL
  • ChEMBL116838 checkY
ChemSpider
  • 11148 checkY
ECHA InfoCard 100.008.907 Edit this at Wikidata
EC Number
  • 209-796-6
Gmelin Reference
391
KEGG
  • C11147 checkY
MeSH Fluoromethane
PubChem CID
  • 11638
UNII
  • 54A9X6F0CM checkY
UN number UN 2454
CompTox Dashboard (EPA)
  • DTXSID6060474 Edit this at Wikidata
InChI
  • InChI=1S/CH3F/c1-2/h1H3 checkY
    Key: NBVXSUQYWXRMNV-UHFFFAOYSA-N checkY
  • InChI=1/CH3F/c1-2/h1H3
    Key: NBVXSUQYWXRMNV-UHFFFAOYAF
  • FC
Properties
Chemical formula
CH3F
Molar mass 34.03 g/mol
Appearance Colourless gas
Odor pleasant, ether-like odour at high concentrations
Density 1.4397 g/L

0.557 g/cm3 (liquid) at saturation pressure at 25 °C

Melting point −137.8 °C (−216.0 °F; 135.3 K)[1]
Boiling point −78.4 °C (−109.1 °F; 194.8 K)[1]
1.66 L/kg (2.295 g/L)
Vapor pressure 3.3 MPa
Hazards
GHS labelling:
GHS02: FlammableGHS04: Compressed Gas
Danger
H220, H280
P210, P377, P381, P403, P410+P403
NFPA 704 (fire diamond)
NFPA 704 four-colored diamondHealth 1: Exposure would cause irritation but only minor residual injury. E.g. turpentineFlammability 4: Will rapidly or completely vaporize at normal atmospheric pressure and temperature, or is readily dispersed in air and will burn readily. Flash point below 23 °C (73 °F). E.g. propaneInstability 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g. liquid nitrogenSpecial hazards (white): no code
1
4
0
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
☒N verify (what is checkY☒N ?)
Infobox references
Chemical compound

Fluoromethane, also known as methyl fluoride, Freon 41, Halocarbon-41 and HFC-41, is a non-toxic, liquefiable, and flammable gas at standard temperature and pressure. It is made of carbon, hydrogen, and fluorine. The name stems from the fact that it is methane (CH4) with a fluorine atom substituted for one of the hydrogen atoms. It is used in semiconductor manufacturing processes as an etching gas in plasma etch reactors.[2]

Composition

The compound is the lowest mass member of the hydrofluorocarbon (HFC) family, compounds which contain only hydrogen, fluorine, and carbon. These compounds are related to the chlorofluorocarbons (CFC), but since they do not contain chlorine, are not destructive to the ozone layer.[3] Fluorocarbons are, however, potent greenhouse gasses, and the Kigali Amendment to the Montreal Protocol is an attempt to phase them out due to their contribution to global warming.[4]

The C−F bond energy is 552 kJ/mol and its length is 0.139 nm. Its molecular geometry is tetrahedral. Its Dipole Moment is 1.85 D.[citation needed]

Its specific heat capacity (Cp) is 38.171 J·mol−1·K−1 at 25 °C. The critical point of fluoromethane is at 44.9 °C (318.1 K) and 6.280 MPa.

See also

References

  1. ^ a b Record in the GESTIS Substance Database of the Institute for Occupational Safety and Health
  2. ^ Siegemund, Günter; Schwertfeger, Werner; Feiring, Andrew; Smart, Bruce; Behr, Fred; Vogel, Herward; McKusick, Blaine (2002). "Fluorine Compounds, Organic". Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH. doi:10.1002/14356007.a11_349. ISBN 978-3527306732.
  3. ^ Fluoromethane CH3F
  4. ^ "Explainer: hydrofluorocarbons saved the ozone layer, so why are we banning them?". 2 November 2017.
  • Thermochemical data at chemnet.ru
  • v
  • t
  • e
Unsubstituted
  • CH4
Monosubstituted
  • CH3F
  • CH3Cl
  • CH3Br
  • CH3I
  • CH3At
Disubstituted
  • CH2F2
  • CH2ClF
  • CH2BrF
  • CH2FI
  • CH2Cl2
  • CH2BrCl
  • CH2ClI
  • CH2Br2
  • CH2BrI
  • CH2I2
Trisubstituted
  • CHF3
  • CHClF2
  • CHBrF2
  • CHF2I
  • CHCl2F
  • C*HBrClF
  • C*HClFI
  • CHBr2F
  • C*HBrFI
  • CHFI2
  • CHCl3
  • CHBrCl2
  • CHCl2I
  • CHBr2Cl
  • C*HBrClI
  • CHClI2
  • CHBr3
  • CHBr2I
  • CHBrI2
  • CHI3
Tetrasubstituted
  • CF4
  • CClF3
  • CBrF3
  • CF3I
  • CCl2F2
  • CBrClF2
  • CClF2I
  • CBr2F2
  • CBrF2I
  • CF2I2
  • CCl3F
  • CBrCl2F
  • CCl2FI
  • CBr2ClF
  • C*BrClFI
  • CClFI2
  • CBr3F
  • CBr2FI
  • CBrFI2
  • CFI3
  • CCl4
  • CBrCl3
  • CCl3I
  • CBr2Cl2
  • CBrCl2I
  • CCl2I2
  • CBr3Cl
  • CBr2ClI
  • CBrClI2
  • CClI3
  • CBr4
  • CBr3I
  • CBr2I2
  • CBrI3
  • CI4
* Chiral compound.
  • v
  • t
  • e
  • v
  • t
  • e
Salts and covalent derivatives of the fluoride ion
HF ?HeF2
LiF BeF2 BF
BF3
B2F4
+BO3
CF4
CxFy
+CO3
NF3
FN3
N2F2
NF
N2F4
NF2
?NF5
OF2
O2F2
OF
O3F2
O4F2
?OF4
F2 Ne
NaF MgF2 AlF
AlF3
SiF4 P2F4
PF3
PF5
S2F2
SF2
S2F4
SF3
SF4
S2F10
SF6
+SO4
ClF
ClF3
ClF5
?ArF2
?ArF4
KF CaF
CaF2
ScF3 TiF2
TiF3
TiF4
VF2
VF3
VF4
VF5
CrF2
CrF3
CrF4
CrF5
?CrF6
MnF2
MnF3
MnF4
?MnF5
FeF2
FeF3
FeF4
CoF2
CoF3
CoF4
NiF2
NiF3
NiF4
CuF
CuF2
?CuF3
ZnF2 GaF2
GaF3
GeF2
GeF4
AsF3
AsF5
Se2F2
SeF4
SeF6
+SeO3
BrF
BrF3
BrF5
KrF2
?KrF4
?KrF6
RbF SrF
SrF2
YF3 ZrF2
ZrF3
ZrF4
NbF4
NbF5
MoF4
MoF5
MoF6
TcF4
TcF
5

TcF6
RuF3
RuF
4

RuF5
RuF6
RhF3
RhF4
RhF5
RhF6
PdF2
Pd[PdF6]
PdF4
?PdF6
Ag2F
AgF
AgF2
AgF3
CdF2 InF
InF3
SnF2
SnF4
SbF3
SbF5
TeF4
?Te2F10
TeF6
+TeO3
IF
IF3
IF5
IF7
+IO3
XeF2
XeF4
XeF6
?XeF8
CsF BaF2   LuF3 HfF4 TaF5 WF4
WF5
WF6
ReF4
ReF5
ReF6
ReF7
OsF4
OsF5
OsF6
?OsF
7

?OsF
8
IrF2
IrF3
IrF4
IrF5
IrF6
PtF2
Pt[PtF6]
PtF4
PtF5
PtF6
AuF
AuF3
Au2F10
?AuF6
AuF5•F2
Hg2F2
HgF2
?HgF4
TlF
TlF3
PbF2
PbF4
BiF3
BiF5
?PoF2
PoF4
PoF6
AtF
?AtF3
?AtF5
RnF2
?RnF
4

?RnF
6
FrF RaF2   LrF3 Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
LaF3 CeF3
CeF4
PrF3
PrF4
NdF2
NdF3
NdF4
PmF3 SmF2
SmF3
EuF2
EuF3
GdF3 TbF3
TbF4
DyF2
DyF3
DyF4
HoF3 ErF3 TmF2
TmF3
YbF2
YbF3
AcF3 ThF3
ThF4
PaF4
PaF5
UF3
UF4
UF5
UF6
NpF3
NpF4
NpF5
NpF6
PuF3
PuF4
PuF5
PuF6
AmF2
AmF3
AmF4
?AmF6
CmF3
CmF4
 ?CmF6
BkF3
BkF
4
CfF3
CfF4
EsF3
EsF4
?EsF6
Fm Md No
PF6, AsF6, SbF6 compounds
  • AgPF6
  • KAsF6
  • LiAsF6
  • NaAsF6
  • HPF6
  • HSbF6
  • NH4PF6
  • LiSbF6
  • KPF6
  • KSbF6
  • LiPF6
  • NaPF6
  • NaSbF6
  • TlPF6
AlF6 compounds
  • (NH4)3[AlF6]
  • Cs2AlF5
  • Li3AlF6
  • K3AlF6
  • Na3AlF6
chlorides, bromides, iodides
and pseudohalogenides
SiF62-, GeF62- compounds
  • BaSiF6
  • BaGeF6
  • (NH4)2SiF6
  • Na2[SiF6]
  • K2[SiF6]
  • Li2GeF6
  • Li2SiF6
Oxyfluorides
  • BrOF3
  • BrO2F
  • BrO3F
  • LaOF
  • ThOF2
  • VOF
    3
  • TcO
    3
    F
  • WOF
    4
  • YOF
  • ClOF3
  • ClO2F3
Organofluorides
  • CBrF3
  • CBr2F2
  • CBr3F
  • CClF3
  • CCl2F2
  • CCl3F
  • CF2O
  • CF3I
  • CHF3
  • CH2F2
  • CH3F
  • C2Cl3F3
  • C2H3F
  • C6H5F
  • C7H5F3
  • C15F33N
  • C3H5F
  • C6H11F
with transition metal,
lanthanide, actinide, ammonium
  • VOF3
  • CrOF4
  • CrF2O2
  • NH4F
  • (NH4)3CrF6
  • (NH4)3GaF6
  • (NH4)2GeF6
  • (NH4)3FeF6
  • (NH4)3InF6
  • NH4NbF6
  • (NH4)2SnF6
  • NH4TaF6
  • (NH4)3VF6
  • (NH4)2ZrF6
  • CsXeF7
  • Li2SnF6
  • Li2TiF6
  • LiWF6
  • Li2ZrF6
  • K2TiF6
  • Rb2TiF6
  • Na2TiF6
  • Na2ZrF6
  • K2NbF7
  • K2TaF7
  • K2ZrF6
  • UO2F2
nitric acids
bifluorides
  • KHF2
  • NaHF2
  • NH4HF2
thionyl, phosphoryl,
and iodosyl
  • F2OS
  • F3OP
  • PSF3
  • IOF3
  • IO3F
  • IOF5
  • IO2F
  • IO2F3
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