Hemihedrite

(repeating unit)Pb10Zn(CrO4)6(SiO4)2(F,OH)2IMA symbolHhe[1]Strunz classification7.FC.15Crystal systemTriclinicSpace groupP1 (No. 2)Unit cella = 9.49, b = 11.44
c = 10.84 [Å]; α = 120.5°
β = 92.1°, γ = 55.83°; Z = 1IdentificationColorBright orange, henna-brown, to almost blackCrystal habitEuhedral crystals with hemihedral morphologyTwinningPresentMohs scale hardness3LusterVitreousStreakSaffron-yellowDiaphaneityTranslucent to transparentSpecific gravity6.42Optical propertiesBiaxial (+)Refractive indexnα = 2.105 nβ = 2.320 nγ = 2.650Birefringenceδ = 0.545PleochroismFeeble, yellow to orange2V angle88° (measured)References[2][3][4][5][6]

Hemihedrite is a rare lead zinc chromate silicate mineral with formula Pb10Zn(CrO4)6(SiO4)2(F,OH)2. It forms a series with the copper analogue iranite.[3]

Discovery and occurrence

Hemihedrite was first described in 1967 for occurrences in the Florence lead silver mine in the Ripsey District, Tortilla Mountains, Pinal County, Arizona, US.[3] It was named for the hemihedral morphology of its crystals.[2]

It occurs in oxidized veins containing galena, sphalerite and pyrite. Associated secondary minerals include cerussite, phoenicochroite, vauquelinite, willemite, wulfenite, galena, sphalerite, pyrite, tennantite and chalcopyrite.[2] It has been reported from several mining districts in Arizona and one in Nevada. It has also been reported from the Antofagasta Region of Chile and the Anarak District of Esfahan Province, Iran.[3]


References

  1. ^ Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi:10.1180/mgm.2021.43. S2CID 235729616.
  2. ^ a b c Handbook of Mineralogy
  3. ^ a b c d Hemihedrite on Mindat.org
  4. ^ Hemihedrite data on Webmineral
  5. ^ Mineralienatlas
  6. ^ McLean, W.J.; Anthony, J.W. (1970). "The crystal structure of hemihedrite". American Mineralogist. 55: 1103–1114.


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