Iodine monobromide
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Names | |
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IUPAC name Iodine monobromide | |
Other names Iodine bromide | |
Identifiers | |
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3D model (JSmol) |
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ChemSpider |
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ECHA InfoCard | 100.029.236 ![]() |
PubChem CID |
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CompTox Dashboard (EPA) |
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InChI
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Properties | |
Chemical formula | IBr |
Molar mass | 206.904 g/mol |
Appearance | dark red solid |
Melting point | 42 °C (108 °F; 315 K) |
Boiling point | 116 °C (241 °F; 389 K) |
Related compounds | |
Other anions | iodine monochloride, iodine monofluoride |
Related interhalogen compounds | Iodine monochloride Iodine monofluoride Bromine monochloride |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). ![]() ![]() ![]() Infobox references |
Chemical compound
Iodine monobromide is an interhalogen compound with the formula IBr. It is a dark red solid that melts near room temperature.[1] Like iodine monochloride, IBr is used in some types of iodometry. It serves as a source of I+. Its Lewis acid properties are compared with those of ICl and I2 in the ECW model. It can form CT adducts with Lewis donors.[2]
Iodine monobromide is formed when iodine and bromine are combined in a chemical reaction:.[3]
- I2 + Br2 → 2 IBr
References
- ^ Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. ISBN 978-0-08-037941-8.
- ^ Aragoni, M. Carla; Arca, Massimiliano; Demartin, Francesco; Devillanova, Francesco A.; Garau, Alessandra; Isaia, Francesco; Lippolis, Vito; Verani, Gaetano (2005-06-16). "DFT calculations, structural and spectroscopic studies on the products formed between IBr and N,N′-dimethylbenzoimidazole-2(3H)-thione and -2(3H)-selone". Dalton Transactions (13): 2252–2258. doi:10.1039/B503883A. ISSN 1477-9234. PMID 15962045.
- ^ M. Schmeisser (1963). "Iodine bromide IBr". In G. Brauer (ed.). Handbook of Preparative Inorganic Chemistry, 2nd Ed. Vol. 1. NY, NY: Academic Press. p. 291.
- v
- t
- e
- HIO2
- ICl3
- IF3
- IBr3
- I2(SO4)3
- IO
2
- HIO3
- IF5
- I2O5
- IO2F
- IOF3
- HIO4
- H5IO6
- IF7
- IO3F
- IO2F3
- IOF5