1,1'-二茂铁二甲酸 |
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识别 |
CAS号 | 1293-87-4 Y |
SMILES | - [Fe+2].[cH-]1cccc1C(O)=O.[cH-]2cccc2C(O)=O
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性质 |
化学式 | C12H10FeO4 |
摩尔质量 | 274.05 g·mol−1 |
熔点 | >250 °C(分解) |
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。 |
1,1'-二茂铁二甲酸是一种有机化合物,化学式为C12H10FeO4。它可由1,1'-二乙酰基二茂铁和次氯酸钠溶液反应制得。[1]它具有羧酸的通性,如和草酰氯反应,可以得到1,1'-二茂铁二甲酰氯;[2]和金属盐反应,生成二茂铁二甲酸的盐[3]。
参考文献
- ^ Bo Gao, Bingqin Yang, Tao Li, Binglin Zhang. Synthesis and Characterization of Ester Ferrocenophanes. Synthetic Communications. 2009-07-21, 39 (16): 2973–2981 [2020-12-24]. ISSN 0039-7911. doi:10.1080/00397910802716150 (英语).
- ^ Muhammad Usman, Haojie Yu, Li Wang, Pavel A. Zhizhko, Dmitry A. Lemenovskiy, Dmitry N. Zarubin, Amin Khan, Kaleem-ur-Rehman Naveed, Ahsan Nazir, Shah Fahad. Synthesis of ferrocenylated-aminopyridines and ferrocenylated-aminothiazoles and their anti-migration and burning rate catalytic properties. Journal of Organometallic Chemistry. 2020-08, 920: 121336 [2020-12-24]. doi:10.1016/j.jorganchem.2020.121336 (英语).
- ^ Jiyang Liu, Haojie Yu, Li Wang. Effective reduction of 4-nitrophenol with Au NPs loaded ultrathin two dimensional metal-organic framework nanosheets. Applied Catalysis A: General. 2020-06, 599: 117605 [2020-12-24]. doi:10.1016/j.apcata.2020.117605 (英语).
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| 全取代金属茂 | 二茂 | - Be(C5H5)2
- Mg(C5H5)2
- V(C5H5)2
- Cr(C5H5)2
- Mn(C5H5)2
- Fe(C5H5)2
- Co(C5H5)2
- Ni(C5H5)2
- Ru(C5H5)2
- Rh(C5H5)2
- Sn(C5H5)2
- Os(C5H5)2
- Pb(C5H5)2
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| 三茂 | - Sc(C5H5)3
- Y(C5H5)3
- La(C5H5)3
- Ce(C5H5)3
- Pr(C5H5)3
- Nd(C5H5)3
- Pm(C5H5)3
- Sm(C5H5)3
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| 四茂 | |
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| 金属茂盐 | - C5H5-Na+
- C5H5-Li+
- C5H5-In+
- C5H5-Tl+
- [Fe(C5H5)2]BF4
- [Fe(C5H5)2]PF6
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| 金属茂配合物 | - (C5H5)2W2(CO)6
- (C5H5)2Mo2(CO)6
- (C5H5)2Cr2(CO)6
- (C5H5)2Ti(CO)2
- (C5H5)2TiS5
- [(C5H5)2TiCl]2(英语:Bis(cyclopentadienyl)titanium(III)_chloride)
- (C5H5)2TiCl2
- (C5H5)2HfCl2
- (C5H5)2ZrCl2
- (C5H5)2VCl2
- (C5H5)2NbCl2
- (C5H5)2MoCl2
- (C5H5)3NpCl
- (C5H5)2ScCl
- (C5H5)2YCl
- [(C5H5)Fe(CO)2]2(英语:Cyclopentadienyliron_dicarbonyl_dimer)
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| 金属茂衍生物 | - FeCp(Cp-Ac)
- C5H5FeC5H4CHO
- C5H5FeC5H4COOH
- Fe(C5H4COOH)2
- Fe[Cp(PPh2)]2
- Cp*NbCl4
- Cp*TaCl4
- Cp*2V
- Cp*2Fe
- Cp*2Co
- Cp*2Zn2
- Cp*2Ru
- Cp*TiCl3(英语:(Pentamethylclopentadienyl)titanium_trichloride)
- Cp*2TiCl2(英语:Decamethyltitanocene dichloride)
- Cp*2ZrCl2(英语:Decamethylzirconocene_dichloride)
- (Cp*RuCl)2
- (Cp*RhCl)2
- (Cp*IrCl)2
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